Chapter #11 – Lecture notes

 

SECTION #1 – DEVELOPMENT OF THE ATOMIC THEORY

The atom is the smallest particle of an element that has all the properties of that element.  Since atoms are so small, scientists develop models to represent them.  In science, a model is a tool used to visualize something that cannot be seen.

HISTORY OF THE ATOMIC MODEL

A)  DEMOCRITUS

The first person to develop a model of the atom was Democritus.  His model stated that all matter was made up of small indivisible particles called atoms.  He also stated that atoms of different elements had different sizes and shapes.

B) DALTON

In the early 1800’s, a British scientist, named John Dalton, developed a model he called the atomic theory.  This theory has 4 main points.

                  1)  All matter is made up of tiny particles called atoms.
                  2)  Atoms cannot be created or destroyed.

                  3)  Atoms of the same element have the same properties, and atoms of different 
                       elements have different properties.
                  4)  Atoms of different elements can combine to form new
                       substances.

C) THOMSON

In the early 1900’s, a British physicist, named J.J. Thomson, discovered that the atom contained particles with a negative charge.  He called these particles electrons.  He also discovered that somewhere in the atom there must be an equal number pf positively charged particles.

D) RUTHERFORD

In 1911, a physicist from New Zealand, named Ernest Rutherford took Thomson’s model one step further.  He stated that all the positive charge of the atom was located at a very small point in the center of the atom.  He called this point the nucleus.  He called the positively charged particles protons.  He also stated that the electrons were circling around outside the nucleus and that most of the atom was empty space.

E  BOHR

In 1913, a Danish physicist named Niels Bohr, took Rutherford's theory to the final step.  He stated that the electrons move around the nucleus in definite paths.  Each path being a certain distance from the nucleus.  The distance between the paths were not the same.  He called these paths energy levels and stated that the electrons were found in the energy levels and not between them.  The electrons in each energy level have a definite distance from the nucleus.  The farther the energy level is from the nucleus, the greater the amount of energy they have.  He also found out that the electrons can move from one energy level to another.  If the atom absorbs energy, the electron moves away from the nucleus.  If the electron moves closer to the nucleus the atom gives off energy.

**  All these points put together form our modern day atomic theory.

SECTION #2 – THE ATOM

ATOMIC STRUCTURE

Matter exists in 3 possible forms, as elements, as compounds, and as mixtures.  Some common elements are Hydrogen (H), Helium (He), Uranium (U), Sodium (Na), Chlorine (Cl), Zinc (Zn), and Oxygen (O).  Mercury is the only element that exists as a liquid at room temperature.  The atom has 2 main areas, the nucleus which is the center and the largest part, and the electrons, which circle around outside the nucleus.  The atom has 3 main subatomic particles.

I)  PROTONS,

     a.  Symbol is “p”
     b.  Located in the nucleus
     c.  Largest of the 3 main subatomic particles
     d.  Has a positive electrical charge
     e.  The number of protons is the atomic number

II)  NEUTRONS,

     a.  Symbol is a “n”
     b.  Located in the nucleus
     c.  Almost as large as a proton
     d.  They are electrically neutral (no charge)
     e.  The number of protons plus the number of neutrons equals the
          atomic weight.
     f.   Since the neutrons are have no charge, the nucleus of the
          atom is positive.
     g.  Hydrogen is the only atom without a neutron


III)  ELECTRONS


     a.  Symbol is an “e”
     b.  Located outside the nucleus
     c.  They have a negative electrical charge
     d.  They are the smallest of the 3 main subatomic particles
     e.  In all single, uncombined atoms, the number of electrons
          equals the number of protons.  This makes them electrically
          neutral.
     f.  They circle the nucleus in areas called energy levels or shells
     g.  The first shell is the “K” shell, it holds a maximum of 2
          electrons
          The second shell is the “L” shell, it holds a maximum of 8
          electrons.
          The third shell is the “M” shell, it holds a maximum 18
          electrons
          The fourth shell is the “N” shell, it holds a maximum of 32
          electrons.
          All shells after that go alphabetically, and to find the number
          of electrons there, look them up on the periodic table of
          elements.

The nucleus contains other subatomic particles such as the positron, the meson, the neutrino, and the quark.  The SI unit used to express the masses of particles in the atom is the AMU (atomic mass unit).  Scientist have assigned each proton a mass of one AMU.  Remember that mass number and atomic weight mean the same thing.  Under certain conditions atoms of an element may not be the same.  These atoms are called isotopes.  Isotopes are atoms that have the same number of protons, (which give the atom its identity), but different numbers of neutrons.  Atoms that are isotopes of each other are always the same element because they have the same number of protons.


FORCES IN THE ATOM


There are 4 main forces that act within the atom:

     a.  Gravity – this force is very small within the atom.
     b.  Electromagnetic Force – this force is responsible for keeping
          the electrons in orbit around the nucleus.  This occurs because
          of the attraction between the negative electrons and the
          positive nucleus.
     c.  Strong Force – this force is responsible for keeping the
          nucleus together.
     d.  Weak Force – this force is believed to play a key role in
          allowing atoms to change when they combine with other atoms.

MAKING MODELS OF THE ATOM

RULES FOR MAKING ATOMIC MODELS:

1.      Make a data table.  Using the periodic table of elements, find the information needed to fill out the data table.  This include the number of protons, neutrons, and the electron configuration.  Remember, to find the number of protons, look up the atomic number.  To find the number of neutrons, round off the atomic weight and subtract the atomic number.  The electron configuration, located in the upper left hand corner of each box on the periodic table, tells you the number of shells, the order they are in, top number is the first shell (closest to the nucleus), and the number of electrons located in each shell.

2.      Draw in the nucleus

3.      Draw in the proper number of electron shells.

4.   Draw in the electrons using the pattern, top, bottom, right, left.